87025-34-1

Basic information

• Product Name: Propane, 2-methoxy-2-(1-methylethoxy)-
• CAS NO: 87025-34-1
• Molecular Formula: C7H16O2
• Molecular Weight: 132.203
• Mol File: 87025-34-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Propane, 2-methoxy-2-(1-methylethoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Propane, 2-methoxy-2-(1-methylethoxy)-(87025-34-1)
• EPA Substance Registry System: Propane, 2-methoxy-2-(1-methylethoxy)-(87025-34-1)

Safety Data

• Hazardous Substances Data: 87025-34-1(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 108-20-3 di-isopropyl ether 

Relevant articles and documents

INDIRECT ELECTROCHEMICAL α-METHOXYLATION OF ALIPHATIC ETHERS AND ACETALS - REACTIVITY AND REGIOSELECTIVITY OF THE ANODIC OXIDATION USING TRIS(2,4-DIBROMOPHENYL)AMINE AS REDOX CATALYST

The technically important α-methoxylation of aliphatic ethers and acetals to form mixed acetals respectively aldehydes or ortho-esters can be performed electrochemically at low potentials in methanol solution using an undivided cell and tris(2,4-dibromophenyl)amine as redox catalyst.The regioselectivity is usually considerably higher as compared with direct electrolysis in the abscence of a catalyst.Especially valuable is the method for the regioselective methoxylation of secondary carbon atoms in presence of primary or tertiary ones and of the acetal carbon in 1,3-dioxolanes.The redox catalyst is stable under the reaction conditions so that more than thousand turnovers could be obtained.