870285-33-9Relevant academic research and scientific papers
The difference in reactivity of (-)-mono and dimenthyl vs. diethyl alkylphosphonates in the α-lithiation reaction: Carbanionic synthesis of unknown (-)-dimenthyl 1-iodoalkylphosphonates and their first use in the radical iodine atom transfer addition (I-A
Ba?czewski, Piotr,Szadowiak, Aldona,Bodzioch, Agnieszka,Bia?as, Tomasz,Wieczorek, Wanda M.,Szyrej, Ma?gorzata
, p. 997 - 1009 (2007/10/03)
Unknown (-)-dimenthyl and ethyl (-)-menthyl 1-iodoethylphosphonates were synthesized via 1-lithio derivatives in 85-87% yields. Starting (-)-dimenthyl alkylphosphonates (R = Me, Et, i-Pr) were obtained in the Michaelis-Becker reaction (75-81% yields) and/
