900537-07-7

Basic information

• Product Name: di(1R,2S,5R)-menthyl methylphosphonate
• Synonyms: di(1R,2S,5R)-menthyl methylphosphonate
• CAS NO: 900537-07-7
• Molecular Weight: 372.529
• Mol File: 900537-07-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: di(1R,2S,5R)-menthyl methylphosphonate(CAS DataBase Reference)
• NIST Chemistry Reference: di(1R,2S,5R)-menthyl methylphosphonate(900537-07-7)
• EPA Substance Registry System: di(1R,2S,5R)-menthyl methylphosphonate(900537-07-7)

Safety Data

• Hazardous Substances Data: 900537-07-7(Hazardous Substances Data)

Upstream product

• 105449-76-1 di(1R,2S,5R)-menthyl phosphorochloridite 
• 2216-51-5 (-)-menthol 
• 676-97-1 methylphosphonic acid dichloroanhydride 
• 211183-18-5 hydrogen di[(1R,2S,5R)-menthyl] phosphite 
• 74-88-4 methyl iodide 

Downstream Products

• 930596-97-7 (-)-dimenthyl ethylphosphonate 
• 930597-05-0 (-)-dimenthyl 1-iodo-1-methyl-6-trimethylsilyl-n-hex-5-ynylphosphonate 
• 930597-04-9 (-)-dimenthyl 1-methyl-6-trimethylsilyl-n-hex-5-ynylphosphonate 
• 930596-99-9 (1-iodo-1-trimethylsilanyl-ethyl)-phosphonic acid bis-(2-isopropyl-5-methyl-cyclohexyl) ester 
• 870285-33-9 (1-iodo-ethyl)-phosphonic acid bis-(2-isopropyl-5-methyl-cyclohexyl) ester 
• 945652-64-2 di(1R,2S,5R)-menthyl (2R)-2-hydroxy-3-azidopropylphosphonate 
• 945652-62-0 bis[(1R,2S,5R)-menthyl] [(2R)-3-(dibenzylamino)-2-hydroxypropyl]phosphonate 
• 945652-61-9 bis[(1R,2S,5R)-menthyl] (2R)-(oxiran-2-yl)-methylphosphonate 
• 945652-59-5 di(1R,2S,5R)-menthyl [(R)-2-hydroxy-3-chloropropyl]phosphonate 
• 900537-05-5 bis[(1R,2S,5R)-menthyl] ((S)-3-chloro-2-hydroxypropyl)phosphonate 
• 900537-08-8 di(1R,2S,5R)-menthyl 2-keto-3-chloropropylphosphonate 

Relevant articles and documents

The difference in reactivity of (-)-mono and dimenthyl vs. diethyl alkylphosphonates in the α-lithiation reaction: Carbanionic synthesis of unknown (-)-dimenthyl 1-iodoalkylphosphonates and their first use in the radical iodine atom transfer addition (I-A

Unknown (-)-dimenthyl and ethyl (-)-menthyl 1-iodoethylphosphonates were synthesized via 1-lithio derivatives in 85-87% yields. Starting (-)-dimenthyl alkylphosphonates (R = Me, Et, i-Pr) were obtained in the Michaelis-Becker reaction (75-81% yields) and/

Di(1R,2S,5R)-menthyl 2-hydroxy-3-chloropropylphosphonate as a useful chiral synthon for the preparation of enantiomerically pure phosphonic acids

Stereochemically pure di(1R,2S,5R)-menthyl (S)- and (R)-2-hydroxy-3- chloropropylphosphonates were synthesized by reaction of di(1R,2S,5R)-menthyl ketophosphonate with chiral complexes prepared from sodium borohydride and (R,R)-(+)-tartaric acid or with (