870465-34-2Relevant academic research and scientific papers
Studies on the mechanism of action of prekinamycin, a member of the diazoparaquinone family of natural products: Evidence for both sp2 radical and orthoquinonemethide intermediates
Feldman, Ken S.,Eastman, Kyle J.
, p. 12562 - 12573 (2006)
The putative reductive activation chemistry of the diazoparaquinone antibiotics was modeled with Bu3Sn-H and prekinamycin dimethyl ether along with prekinamycin itself. Reaction in various combinations of aromatic solvents, with and without the
A proposal for the mechanism-of-action of diazoparaquinone natural products
Feldman, Ken S.,Eastman, Kyle J.
, p. 15344 - 15345 (2007/10/03)
Treatment of the representative diazoparaquinone prekinamycin dimethyl ether with Bu3SnH/AIBN in aromatic solvents furnishes moderate-to-good yields of formal aryl adducts wherein a molecule of solvent is attached to the carbon (C(11)) previous
