87051-12-5

Basic information

• Product Name: (4aRS,7aRS)-4a,7a-dihydro-3,3-dimethyl-6,7a-diphenyl-7H-cyclopenta<1,2-e><1,2,4>trioxine
• Synonyms: (4aRS,7aRS)-4a,7a-dihydro-3,3-dimethyl-6,7a-diphenyl-7H-cyclopenta<1,2-e><1,2,4>trioxine
• CAS NO: 87051-12-5
• Molecular Weight: 308.377
• Mol File: 87051-12-5.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (4aRS,7aRS)-4a,7a-dihydro-3,3-dimethyl-6,7a-diphenyl-7H-cyclopenta<1,2-e><1,2,4>trioxine(CAS DataBase Reference)
• NIST Chemistry Reference: (4aRS,7aRS)-4a,7a-dihydro-3,3-dimethyl-6,7a-diphenyl-7H-cyclopenta<1,2-e><1,2,4>trioxine(87051-12-5)
• EPA Substance Registry System: (4aRS,7aRS)-4a,7a-dihydro-3,3-dimethyl-6,7a-diphenyl-7H-cyclopenta<1,2-e><1,2,4>trioxine(87051-12-5)

Safety Data

• Hazardous Substances Data: 87051-12-5(Hazardous Substances Data)

Upstream product

• 62121-84-0 endoperoxide of 1,4-diphenylcyclopentadiene 
• 67-64-1 acetone 
• 62121-84-0 1,4-diphenyl-2,3-dioxabicyclo[2.2.1]hept-5-ene 

Downstream Products

• 114390-60-2 (1RS,2RS)-1,4-diphenylcyclopent-3-en-1,2 diol 
• 67-64-1 acetone 

Relevant articles and documents

Intramolecular Oxygen Transfer on the Ozonolysis of a Diphenylcyclopentene Derivative

The ozonolysis of cis-3,4a,7,7a-tetrahydro-3,3-dimethyl-6,7a-diphenylcyclopentatrioxine (1) in CH2Cl2 at -78 deg gave the secondary endo ozonide 2 (43percent yield) and an acetal 3 (27percent yield) derived from O-insertion at the ortho posi

Reactions of Cyclic Peroxides with Aldehydes and Ketones catalysed by Trimethylsilyl Trifluoromethanesulphonate. An Efficient Synthesis of 1,2,4-Trioxanes

Trimethylsilyl trifluoromethanesulphonate is found to be an efficient catalyst for the reaction of 1,4-endoperoxides and 1,2-dioxetanes with aldehydes and ketones to give 1,2,4-trioxanes in high yields.