870533-29-2

Upstream product

• 1309478-53-2 C₁₉H₁₇FN₂O₃ 
• 72-18-4 L-valine 
• 5511-73-9 N-phthalimide l-valinyl chloride 
• 6306-54-3 N-phthaloyl L-valine 
• 13734-41-3 t-Boc-L-valine 
• 371-40-4 4-fluoroaniline 
• 870533-24-7 tert-butyl (S)-(1-((4-fluorophenyl)amino)-3-methyl-1-oxobutan-2-yl)carbamate 

Downstream Products

• 1309478-56-5 C₁₁H₁₇FN₂ 

Relevant academic research and scientific papers

Electrostatic repulsion and hydrogen-bonding interactions in a simple N-aryl-L-valinamide organocatalyst control the stereoselectivity in asymmetric aldol reactions

A novel stereocontrol method for asymmetric aldol reactions of aldehydes with ketones is described. The stereoselectivity of the products is controlled by the electrostatic repulsion and hydrogen-bonding interactions of an N-aryl-L-valinamide catalyst. Th

Chiral calcium catalysts for asymmetric hydroamination/cyclisation

Calcium complexes supported by chiral 1,2-diamines have been shown to be efficient catalysts for the asymmetric hydroamination of amino-olefin substrates; the calcium complexes [Ca(NNR){N(SiMe3) 2}(THF)] (R = tBu, iPr, Ph, 4-C 6H4F) give enantioselectivities of up to 26% which marks a significant increase based upon literature precedence. The structure of [Ca(NNPh){N(SiMe3)2}(py)] has been computed with density functional methods.