87064-17-3

Usage

InChI:InChI=1/C16H20O2/c1-12-4-3-5-13(2)11-18-15-8-9-16(17)14(10-15)7-6-12/h5-6,8-10,17H,3-4,7,11H2,1-2H3/b12-6+,13-5+

Upstream product

• 37905-03-6 8-hydroxygeranyl acetate 
• 72705-14-7 8-(2',5'-diacetoxyphenyl)-2,6-dimethyl-2,6-octadien-1-ol 
• 73696-94-3 (2E,6E)-8-<(tert.-Butyl)dimethylsilyloxy>-3,7-dimethylocta-2,6-dien-1-yl Acetate 
• 90663-14-2 (2E,6E)-8-chloro-1-tert-butyldimethylsiloxy-2,6-dimethyl-2,6-octadiene 
• 90460-86-9 (2E,6E)-8-<(tert-Butyl)dimethylsilyloxy>-3,7-dimethylocta-2,6-dien-1-ol 
• 90663-17-5 8-(2',5'-diacetoxyphenyl)-2,6-dimethyl-2,6-octadien-1-ol t-butyldimethylsilyl ether 
• 90663-16-4 8-(2',5'-dihydroxyphenyl)-2,6-dimethyl-2,6-octadiene-1-ol t-butyldimethylsilyl ether 
• 68753-95-7 (2E,6E)-2,6-dimethyldeca-2,6-dien-10-trimethylsilyl-9-yne 
• 105-87-3 3,7-dimethyl-2E,6-octadien-1-yl acetate 
• 924297-36-9 2,6-dimethyl-10-trimethylsilanyl-deca-2,6-dien-9-yn-1-ol 
• 924297-37-0 2,6-dimethyl-deca-2,6-dien-9-yn-1-ol 
• 1112-56-7 tetravinyltin (IV) 
• 924297-38-1 4,8-dimethyl-14-trimethylsilanyl-2-oxa-bicyclo[9.3.1]pentadeca-1⁽¹⁵⁾,4,8,11,13-pentaen-12-ol 
• 90663-18-6 8-(2',5'-diacetoxyphenyl)-2,6-dimethyl-2,6-octadienyl chloride 

Relevant academic research and scientific papers

Application of intramolecular D?tz reaction to the synthesis of ansa-compounds: concise synthesis of arnebinol

Fischer carbene complexes having long alkynyloxy chains regioselectively produced oxametacyclophanes via the intramolecular D?tz reaction. The utility of this reaction was demonstrated in the synthesis of arnebinol, an ansa-type terpenoid, from geranyl acetate in six steps.

SYNTHESIS OF ARNEBINOL, AN INHIBITOR OF PROSTAGLANDIN BIOSYNTHESIS

A new ansa-type compound, arnebinol 1, was synthesized.