87071-03-2

Basic information

• Product Name: Cyclohexanol, 1-(3-hydroxy-1-propenyl)-, (E)-
• CAS NO: 87071-03-2
• Molecular Formula: C9H16O2
• Molecular Weight: 156.225
• Mol File: 87071-03-2.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Cyclohexanol, 1-(3-hydroxy-1-propenyl)-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanol, 1-(3-hydroxy-1-propenyl)-, (E)-(87071-03-2)
• EPA Substance Registry System: Cyclohexanol, 1-(3-hydroxy-1-propenyl)-, (E)-(87071-03-2)

Safety Data

• Hazardous Substances Data: 87071-03-2(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 78-27-3 1-Ethynylcyclohexan-1-ol 
• 87070-89-1 1-[(Z)-3-(Tetrahydro-pyran-2-yloxy)-1-trimethylsilanyl-propenyl]-cyclohexanol 
• 5686-96-4 1-(3-hydroxyprop-1-yn-1-yl)cyclohexan-1-ol 
• 87071-00-9 1-[(E)-3-(Tetrahydro-pyran-2-yloxy)-propenyl]-cyclohexanol 

Downstream Products

• 59906-45-5 1-(1-Hydroxy-allyl)-cyclohexanol 
• 674368-22-0 1-[(E)-3-methoxycarbonyloxy-1-propenyl]cyclohexanol 

Relevant articles and documents

Atom-Transfer Radical Addition of Alcohols to Aliphatic Alkynes

An intermolecular hydrogen bond-promoted atom-transfer radical addition of simple alcohols to aliphatic alkynes is demonstrated here. Through this strategy, a variety of allyl alcohols can be synthesized in high selectivity and yields. Furthermore, this work reveals the relationship between selectivity and the substrate. ?

Palladium-Catalyzed Carbon Dioxide Elimination-Fixation Reaction of 4-Methoxycarbonyloxy-2-buten-1-ols

A new type of palladium-catalyzed CO2 recycling reaction using allylic carbonates is described. Reaction of trans-4-methoxycarbonyloxy-2-buten-1-ols in the presence of a palladium catalyst produces cyclic carbonates having a vinyl group via a CO2 elimination-fixation process. A variety of allylic carbonates participate in the reaction giving cyclic carbonates with high efficiencies. Stereoselective construction of trans-cyclic carbonates is achieved by using nonsymmetric substrates. An enantiospecific reaction proceeds to give chiral cyclic carbonate when a chiral methyl-substituted substrate is subjected to the reaction conditions.