87087-49-8

Basic information

• Product Name: 2-Propenoic acid, 3-[4-(methoxymethyl)phenyl]-, methyl ester
• CAS NO: 87087-49-8
• Molecular Formula: C12H14O3
• Molecular Weight: 206.241
• Mol File: 87087-49-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-Propenoic acid, 3-[4-(methoxymethyl)phenyl]-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenoic acid, 3-[4-(methoxymethyl)phenyl]-, methyl ester(87087-49-8)
• EPA Substance Registry System: 2-Propenoic acid, 3-[4-(methoxymethyl)phenyl]-, methyl ester(87087-49-8)

Safety Data

• Hazardous Substances Data: 87087-49-8(Hazardous Substances Data)

Upstream product

• 91912-54-8 1-iodo-4-(methoxymethyl)benzene 
• 292638-85-8 acrylic acid methyl ester 
• 7560-43-2 methyl 3-(4-methylphenyl)acrylate 
• 67-56-1 methanol 
• 946-99-6 methyl 3-(4-bromomethyl)cinnamate 

Relevant articles and documents

2-Ferrocenyl-2-thiazoline as a building block of novel phosphine-free ligands

New 1,2-disubstituted ferrocenes [5(b-j), in which R = -SMe, -SPh, -SiPr, -SiMe3, -SePh, -SnBu3, -B(OH)2, -Me, -I] with a thiazoline ring in the ferrocene backbone using as key intermediate a ferrocenyl Fischer carbene complex were synthesized. The capability of the 2-thiazoline moiety as an ortho-directed metalation group was demonstrated by subsequent quenching of lithium intermediate with several electrophiles, proving to be an excellent method for synthesizing bidentate ligands. The catalytic scope of the [N,S] ligand 5b as the corresponding palladium complex 5b-PdCl 2 in a microwave-promoted Heck reaction was also tested. Results obtained showed better catalytic activity of 5b-PdCl2 compared to other catalytic systems based on a [N,S] ferrocenyl ligand. The Royal Society of Chemistry.