87095-02-1

Basic information

• Product Name: 2-nitro-1-(3,4-dimethoxyphenyl)propane
• Synonyms: 2-nitro-1-(3,4-dimethoxyphenyl)propane
• CAS NO: 87095-02-1
• Molecular Weight: 225.244
• Mol File: 87095-02-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-nitro-1-(3,4-dimethoxyphenyl)propane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-nitro-1-(3,4-dimethoxyphenyl)propane(87095-02-1)
• EPA Substance Registry System: 2-nitro-1-(3,4-dimethoxyphenyl)propane(87095-02-1)

Safety Data

• Hazardous Substances Data: 87095-02-1(Hazardous Substances Data)

Upstream product

• 122-47-4 1-(3,4-dimethoxyphenyl)-2-nitropropene 
• 37629-53-1 (E)-1,2-dimethoxy-4-(2-nitroprop-1-enyl)benzene 
• 120-14-9 3,4-dimethoxy-benzaldehyde 
• 122-47-4 3,4-dimethoxy-β-methyl-β-nitrostyrene 

Downstream Products

• 120-26-3 2-(3,4-dimethoxyphenyl)-1-methylethylamine 
• 321131-88-8 2-nitro-1-(3,4-dihydroxyphenyl)propane 
• 17254-09-0 3.4-Dimethoxy-1-(2-propionylaminopropyl)-benzol 
• 51920-75-3 N-[2-(3,4-dimethoxy-phenyl)-1-methyl-ethyl]-acetamide 

Relevant articles and documents

Enantioselective hydrogenation of α,β-disubstituted nitroalkenes

The first highly chemo- and enantioselective hydrogenation of α,β-disubstituted nitroalkenes was accomplished with rhodium/JosiPhos-J2 as a catalyst, with the yield and enantioselectivity of up to 95% and 94%, respectively. The α-chiral nitroalkanes will provide an entry to valuable chiral amphetamines which are otherwise not so easily accessed. This journal is the Partner Organisations 2014.

Reaction of a Possible Iminoketene Precursor with 6,7-Dialkoxy-1,3-dialkyl-3,4-dihydroisoquinolines

Reaction of 6,7-dialkoxy-1-alkyl-3,4-dihydro-3-methylisoquinolines (10 - 12) with sulphinamide anhydride (13) yields 2,3-dialkoxy-5,6,7,8-tetrahydro-6-methyl-8-oxoisoquinolinoquinazolines (14 and 19) and 2,3-dialkoxy-13a-alkyl-5,6,7,8,13,13a-hexahydro-6-methyl-8-oxoisoquinolinoquinazolines (15 - 17 and 20).Of the two possible geometrical isomers of the latter class of compounds, the cis-isomer predominates and the trans-isomer is found to be labile towards aerial oxidation.No evidence for the generation of iminoketene (21) is obtained in the reaction of sulphinamide anhydride (13) with various 3,4-dihydroisoquinoline derivatives.