871024-69-0Relevant academic research and scientific papers
A General Method for Imine Formation Using B(OCH2CF3)3
Reeves, Jonathan T.,Visco, Michael D.,Marsini, Maurice A.,Grinberg, Nelu,Busacca, Carl A.,Mattson, Anita E.,Senanayake, Chris H.
supporting information, p. 2442 - 2445 (2015/05/27)
Tris(2,2,2-trifluoroethyl)borate [B(OCH2CF3)3] was found to be a mild and general reagent for the formation of a variety of imines by condensation of amides or amines with carbonyl compounds. N-Sulfinyl, N-toluenesulfonyl,
The first catalytic asymmetric nitro-Mannich-type reaction promoted by a new heterobimetallic complex
Yamada, Ken-Ichi,Harwood, Simon J.,Groeger, Harald,Shibasaki, Masakatsu
, p. 3504 - 3506 (2007/10/03)
The best ratio is 1:1:3 for the components Yb, K, and binaphthol in the new heterobimetallic complex, which efficiently catalyzes an asymmetric nitro-Mannich-type reaction. The desired nitro-Mannich products 2 are obtained with up to 91% ee starting from
