871095-01-1

Basic information

• Product Name: 5-((3aS,5R,6R,6aS)-5-(tert-butyldimethylsilyloxy)-6-((E)-4-m-tolylbut-1-enyl)-1,3a,4,5,6,6a-hexahydropentalen-2-yl)pentan-1-ol
• Synonyms: 5-((3aS,5R,6R,6aS)-5-(tert-butyldimethylsilyloxy)-6-((E)-4-m-tolylbut-1-enyl)-1,3a,4,5,6,6a-hexahydropentalen-2-yl)pentan-1-ol
• CAS NO: 871095-01-1
• Molecular Weight: 468.795
• Mol File: 871095-01-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 5-((3aS,5R,6R,6aS)-5-(tert-butyldimethylsilyloxy)-6-((E)-4-m-tolylbut-1-enyl)-1,3a,4,5,6,6a-hexahydropentalen-2-yl)pentan-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 5-((3aS,5R,6R,6aS)-5-(tert-butyldimethylsilyloxy)-6-((E)-4-m-tolylbut-1-enyl)-1,3a,4,5,6,6a-hexahydropentalen-2-yl)pentan-1-ol(871095-01-1)
• EPA Substance Registry System: 5-((3aS,5R,6R,6aS)-5-(tert-butyldimethylsilyloxy)-6-((E)-4-m-tolylbut-1-enyl)-1,3a,4,5,6,6a-hexahydropentalen-2-yl)pentan-1-ol(871095-01-1)

Safety Data

• Hazardous Substances Data: 871095-01-1(Hazardous Substances Data)

Upstream product

• 934968-46-4 tert-butyldimethyl{(2R,3R,3aS,6aS)-5-[5-(tetrahydro-2H-pyran-2-yloxy)pentyl]-3-[(E)-4-m-tolylbut-1-enyl]-1,2,3,3a,4,6a-hexahydropentalen-2-yloxy}silane 
• 620-23-5 m-tolyl aldehyde 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 118375-00-1 (1S,2R,3R,5R)-7,7-(2,2-Dimethyltrimethylenedioxy)-3-hydroxybicyclo<3.3.0>octan-2-carbonsaeure-methylester 
• 131375-63-8 5-(4-methoxybenzyloxy)-1-pentanol 
• 50556-03-1 3-m-tolyl-acrylic acid ethyl ester 
• 111171-94-9 3-(m-methylphenyl)-1-propanol 
• 111-29-5 1 ,5-pentanediol 
• 871094-98-3 tert-butyl((1S,2R,3aS,6aS)-5-(5-(4-methoxybenzyloxy)pentyl)-1-(trityloxymethyl)-1,2,3,3a,6,6a-hexahydropentalen-2-yloxy)dimethylsilane 
• 871094-95-0 (3aS,5R,6S,6aS)-5-(tert-butyldimethylsilyloxy)-6-(trityloxymethyl)-1,3a,4,5,6,6a-hexahydropentalen-2-yl trifluoromethanesulfonate 
• 871095-05-5 ((1S,2R,3aS,6aS)-2-(tert-butyldimethylsilyloxy)-5-(5-(4-methoxybenzyloxy)pentyl)-1,2,3,3a,6,6a-hexahydropentalen-1-yl)methanol 
• 871094-96-1 (3aS,4S,5R,6aR)-5-(tert-butyldimethylsilyloxy)-4-(trityloxymethyl)-hexahydropentalen-2(1H)-one 
• 871094-94-9 (1R,2R,3aS,6aS)-2-(tert-butyldimethylsilyloxy)-5-(5-(4-methoxybenzyloxy)pentyl)-1,2,3,3a,6,6a-hexahydropentalene-1-carbaldehyde 
• 116896-28-7 [(3a'S,4'S,5'R,6a'R)-5'-(tert-butyldimethylsilyloxy)-5,5-dimethylhexahydro-1'H-spiro[[1,3]dioxane-2,2'-pentalen]-4'-yl]methanol 

Downstream Products

• 871095-02-2 5-((3aS,5R,6R,6aS)-5-(tert-butyldimethylsilyloxy)-6-((E)-4-m-tolylbut-1-enyl)-1,3a,4,5,6,6a-hexahydropentalen-2-yl)pentanoic acid 
• 871095-07-7 5-((3aS,5R,6R,6aS)-5-(tert-butyldimethylsilyloxy)-6-((E)-4-m-tolylbut-1-enyl)-1,3a,4,5,6,6a-hexahydropentalen-2-yl)pentanal 

Relevant articles and documents

Asymmetric synthesis of 3-oxa-15-deoxy-16-(m-tolyl)-17,18,19,20- tetranorisocarbacyclin and its neuroprotective analogue 15-deoxy-16-(m-tolyl)- 17,18,19,20-tetranorisocarbacyclin based on the conjugate addition-azoalkene- asymmetric olefination strategy

A fully stereocontrolled synthesis of 3-oxa-15-deoxy-16-(m-tolyl)17,18,19, 20-tetranorisocarbacyclin (3-oxa-15-deoxy-TIC, 7b) and a formal one of 15-deoxy-16-(w-tolyl)-17,18,19,20-tetranorisocarbacyclin (15- deoxy-TIC, 7a) are described. 15Deoxy-TIC is sp