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Triphenylphosphine monohexylborane adduct, also known as PPh3·BHEt3, is a chemical compound formed by the combination of triphenylphosphine (PPh3) and hexylborane (BHEt3). This adduct is widely used as a ligand in various organometallic and organoboron compounds, particularly in transition metal-catalyzed reactions. It plays a crucial role in stabilizing metal complexes and enhancing their catalytic activity. The compound is characterized by its ability to form strong π-bonding interactions with metal centers, which contributes to its effectiveness in various chemical transformations. Triphenylphosphine monohexylborane adduct is also known for its solubility in organic solvents and its stability under a range of reaction conditions, making it a valuable tool in synthetic chemistry.

87115-42-2

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87115-42-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 87115-42-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,7,1,1 and 5 respectively; the second part has 2 digits, 4 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 87115-42:
(7*8)+(6*7)+(5*1)+(4*1)+(3*5)+(2*4)+(1*2)=132
132 % 10 = 2
So 87115-42-2 is a valid CAS Registry Number.

87115-42-2Relevant academic research and scientific papers

Organoboron Compounds, I. - Transformation of Phosphonium Ylides into Phosphane Monoalkylborane Complexes. - Hydroboration Reactions

Bestmann, Hans Juergen,Roeder, Thomas,Suehs, Kurt

, p. 1509 - 1518 (2007/10/02)

Triphenylphosphonium ylides 1 add borane (from 2) with formation of alkylidenetriphenylphosphorane-boranes 3, which rearrange on heating to give the triphenylphosphane-monoalkylborane adducts 6.Compounds 6 can undergo hydroboration reactions.

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