87129-26-8Relevant academic research and scientific papers
Acid-catalyzed transformations of diepoxy derivatives of terpinolene
Salomatina,Yarovaya,Korchagina,Gatilov,Barkhash
, p. 1479 - 1486 (2011)
Transformations of diepoxy derivatives of terpinolene under conditions of homogeneous and heterogeneous acid catalysis were studied. Qualitative and quantitative compositions of the reaction mixtures were found to depend on the acidity of the medium and m
Chiral 2α,4-dihydroxy-1,8-cineole as a possum urinary metabolite
Carman, Raymond M.,Rayner, Anthony C.
, p. 1 - 6 (2007/10/03)
Both enantiomers of 2α,4-dihydroxy-1,8-cineole (2) have been synthesized. The enantiomer present in possum urine is the (-)-(1R,2R,4R)-isomer (2′). This diol is biosynthesized in the possum from (1R,2R,4S)-2α-hydroxy-1,8-cineole (18).
2α,4-Dihydroxy-1,8-cineole. A New Possum Urinary Metabolite
Carman, Raymond M.,Rayner, Anthony C.
, p. 2087 - 2098 (2007/10/02)
2α,4-Dihydroxy-1,8-cineole (2a) is present in the urine of brushtail possums fed a diet enhanced with 1,8-cineole (1).Chemical syntheses of this novel metabolite (2a) and its 2β-epimer (19a) are described.The n.m.r. spectra of various 1,8- and 1,4-cineoles are reported, and literature assignments for C1 and C4 in the 1,4-cineole series are corrected.
Preparation of 2-exo-Hydroxy-7-oxabicyclo[2.2.1]heptanes
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, (2008/06/13)
2-exo-Hydroxy-7-oxabicyclo[2.2.1]heptanes are prepared by treating the corresponding cis-epoxycyclohexanol with acid in an inert solvent or by treating a 3-cyclohexen-1-ol which will produce the corresponding cis-epoxy alcohol successively or concurrently with an oxidizing agent and an acid in an inert solvent.
