87151-56-2Relevant academic research and scientific papers
Spin Trapping of Molecules Adsorbed on Zinc Oxide
Matsuzaki, Tokuo,Uda, Taizo,Kazusaka, Akio,Keulks, George W.,Howe, Russell F.
, p. 7511 - 7513 (1980)
The reactions of the spin trap PBN with hydrogen and propylene adsorbed on ZnO are reported.For hydrogen, evidence is presented that the species trapped are H atoms adsorbed on Zn sites.For propylene, the allyl anion adsorbed on Zn sites reacts with PBN, but the resulting hydroxylamine must be oxidized before a nitroxide radical can be observed.Less than 1percent of adsorbed species are detected by the spin trapping technique.
Substituent Effects on ESR Parameters of α-Phenyl-N-tert-butylnitrone Spin Adducts. Resolution Enhancement and Mass Spectrometry
Pan, Kai,Lin, Chiou-Rong,Ho, Tong-Ing
, p. 632 - 638 (2007/10/02)
The combination of high-performance liquid chromatography (HPLC) and ESR spectrometry was used to isolate the free radicals produced by the reaction of a Grignard reagent with 15 substituted α-phenyl-N-tert-butylnitrones.Long-range hyperfine splitting con
