87162-58-1Relevant academic research and scientific papers
Synthetic Enzymes. Part 2. Catalytyc Asymmetric Epoxidation by means of Polyamino-acids in a Triphase System
Julia, Sebastian,Guixer, Joan,Masana, Jaume,Rocas, Jose
, p. 1317 - 1324 (2007/10/02)
The asymmetric epoxidation of several chalcones and other electron-poor olefins, in the presence of catalytic amounts of poly-(S)-amino-acids in a triphase system with optical yields of up to 96percent is described.The influence of the molecular structure of the catalysts and substrates, the solvent, and the temperature on the stereochemistry is discussed.
