871675-57-9Relevant academic research and scientific papers
Deconjugation of dehydroamino acids: Stereoselective synthesis of racemic (E)-vinylglycines
Alexander, Paul A.,Marsden, Stephen P.,Munoz Subtil, Dulce M.,Reader, John C.
, p. 5433 - 5436 (2007/10/03)
(Chemical Equation Presented) A practical and general two-step synthesis of carbamate-protected (E)-vinylglycines from aliphatic aldehydes is reported. The key step involves the kinetic α-protonation of dianionic dienolates derived from dehydroamino acids
Rapid assembly of the 1-azabicyclo[3.1.0]hexane skeleton of ficellomycin
Paumier,Garcia,Shipman,Muir
, p. 2212 - 2214 (2007/10/03)
The 1-azabicyclo[3.1.0]hexane core of ficellomycin can be assembled in a concise manner by way of a double cyclisation reaction involving in situ generation of an NH aziridine and further intramolecular conjugate addition onto a dehydroamino ester.
