87173-07-7Relevant academic research and scientific papers
STEREOSELECTIVE ELABORATION OF THE ACYL LIGAND IN (η5-C5H5)Fe(CO)(PPh3)(COCH2R) VIA THE ALKYLATION OF THE ANIONS 5-C5H5)Fe(CO)(PPh3)(COCHR)>Li (R = Me, Et)
Baird, Gordon J.,Davies, Stephen G.
, p. C1 - C3 (1983)
The stereoselective elaboration of the acyl ligand in the complexes (η5-C5H5)Fe(CO)(PPh3)(COCH2R) by addition of electrophiles to the anions 5-C5H5)Fe(CO)(PPh3)(COCHR)>Li is described (R = Me, Et).
Stereoselective Carbon-Carbon Bond Formation via Alkylation of 5-C5H5)Fe(PPh3)(CO)(COMe=CHR)> (R = Me, Prn, Ph): X-Ray Crystal Structure of (Z)-5-C5H5)Fe(PPh3)(CO)(COMe=CHMe)>
Baird, Gordon J.,Davies, Stephen G.,Jones, Richard H.,Prout, Keith,Warner, Peter
, p. 745 - 747 (2007/10/02)
5-C5H5)Fe(PPh3)(CO)(Methoxycarbene)>+ complexes, prepared either from terminal acetylenes or from the corresponding acyl complexes, are stereoselectively deprotonated, as evidenced by the crystal structure of (Z)-5-C5H5)Fe(PPh3
