871840-58-3

Upstream product

• 38645-14-6 <2,2-2H2>propane-1,3-diol 
• 100-39-0 benzyl bromide 

Downstream Products

• 1313206-72-2 [2,4,4-⁽²⁾H₃]-4-(benzyloxy)-2-butanol 
• 1313206-71-1 [1,1,1,3,3-⁽²⁾H₅]-4-(benzyloxy)-2-butanol 
• 858970-92-0 ethyl [4,4,6,6,6-⁽²⁾H₅]-5-(benzyloxy)-3-hydroxy-3-methylpentanoate 
• 858970-89-5 [1,1,1,3,3-⁽²⁾H₅]-4-(benzyloxy)-2-butanone 
• 871840-54-9 1-[(but-3-enyloxy)methyl]benzene-2,2-d2 
• 871840-59-4 [2,2-⁽²⁾H₂]-3-(benzyloxy)-1-propanal 

Relevant academic research and scientific papers

Synthesis of deuterated mevalonolactone isotopomers

A synthetic route was developed for the preparation of deuterated mevalonolactones. Using low-cost deuterated reagents, this route allows for the independent introduction of deuterium labeling into any carbon position or into any combination of positions. Following this approach, the synthesis of [6,6,6-2H3]mevalonolactone, [4,4,6,6,6-2H 5]mevalonolact-one, [5,5-2H2]mevalonolactone, [5,5,6,6,6-2H5]mevalonolact-one, and [2,2,6,6,6- 2H5]mevalonolactone is described.

Metal-catalyzed rearrangement of homoallylic ethers to silylmethyl allylic silanes in the presence of a di-tert-butylsilylene source

(Chemical Equation Presented) In examining the scope of the di-rert-butylsilylene transfer to gem-disubstituted alkenes to form silacyclopropanes, we discovered an unprecedented reaction of homoallylic ethers. When silylene transfer was performed at room