872-89-9Relevant articles and documents
Photostimulated telluromethylation
Junk, Thomas,Fronczek, Frank R.
, p. 4361 - 4362 (1996)
Photostimulated reaction of bromo- and iodoarenes with potassium tellurocyanate in dimethylsulfoxide produces aryl methyl tellurides in moderate yields. This method offers facile access to aryltellurium compounds which are difficult to prepare by other methods.
Facile deoxygenation of telluroxides, tellurones and selenones with nickel boride at ambient temperature
Khurana, Jitender M.,Lumb, Anshika
experimental part, p. 96 - 101 (2012/04/17)
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FeCl3-Diorganyl dichalcogenides promoted cyclization of 2-alkynylanisoles to 3-chalcogen benzo[ b ]furans
Gay, Rafaela M.,Manarin, Flavia,Schneider, Caroline C.,Barancelli, Daniela A.,Costa, Michael D.,Zeni, Gilson
supporting information; experimental part, p. 5701 - 5706 (2010/10/03)
A general synthesis of 3-chalcogen benzo[b]furans from the readily available 2-alkynylanisoles, via FeCl3/diorganyl dichalcogenides intramolecular cyclization, has been developed. Aryl and alkyl groups directly bonded to the chalcogen atom were used as cycling agents. The results revealed that the reaction significantly depends on the electronic effects of substituents in the aromatic ring bonded to the selenium atom of the diselenide species. We observed that the pathway of reaction was not sensitive to the nature of substituents in the aromatic ring of anisole since both the electron-donating and the electron-withdrawing groups delivered the products in similar yields. In addition, the obtained heterocycles were readily transformed to more complex products by using a chalcogen/lithium exchange reaction with n-BuLi followed by trapping of the lithium intermediate with aldehydes, furnishing the desired secondary alcohols in good yields.
