872047-98-8Relevant articles and documents
Direct synthesis of B-allyl and B-allenyldiisopinocampheylborane reagents using allyl or propargyl halides and indium metal under Barbier-type conditions
Hirayama, Lacie C.,Haddad, Terra D.,Oliver, Allen G.,Singaram, Bakthan
, p. 4342 - 4353 (2012/06/30)
We report the first one-pot process for the asymmetric addition of allyl, methallyl, and propargyl groups to aldehydes and ketones using B-chlorodiisopinocampheylborane (dDIP-Cl) and indium metal. Under Barbier-type conditions, indium metal was