872089-34-4Relevant academic research and scientific papers
Magnesium Catalysis Mediated Tetrazoles in Desymmetrization Reaction of Aziridines
Li, Dan,Wang, Kezhou,Wang, Linqing,Wang, Yuan,Wang, Pengxin,Liu, Xin,Yang, Dongxu,Wang, Rui
, p. 3211 - 3214 (2017)
A magnesium-catalyzed asymmetric ring-opening reaction of aziridines with substituted tetrazoles is reported. The current protocol proceeds smoothly and gives the corresponding desymmetrization products in high yields and good enantioselectivities. A new
Novel nitrogen containing chelating ligands from aziridines -Preparation, coordination studies, and catalytic application in the cyclopropanation of styrene
Krasnova, Larissa B.,Yudin, Andrei K.
, p. 1025 - 1032 (2007/10/03)
Novel ligands have been synthesized by the reaction of readily available aziridines with appropriate nitrogen based nucleophiles under mild conditions. Complexes of different stoichiometry can be readily obtained upon reaction between these ligands and the corresponding copper salts. The enantiomerically pure form of one of the ligands was obtained and applied in the styrene cyclopropanation reaction, where the copper catalyst revealed unexpectedly high diastereoselectivity in comparison with the known systems.
