872104-47-7

Basic information

• Product Name: 9,10-bis{[6-(diphenylphosphanyl)-2-pyridylmethyl]propylaminomethyl}anthracene
• Synonyms: 9,10-bis{[6-(diphenylphosphanyl)-2-pyridylmethyl]propylaminomethyl}anthracene
• CAS NO: 872104-47-7
• Molecular Weight: 871.057
• Mol File: 872104-47-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 9,10-bis{[6-(diphenylphosphanyl)-2-pyridylmethyl]propylaminomethyl}anthracene(CAS DataBase Reference)
• NIST Chemistry Reference: 9,10-bis{[6-(diphenylphosphanyl)-2-pyridylmethyl]propylaminomethyl}anthracene(872104-47-7)
• EPA Substance Registry System: 9,10-bis{[6-(diphenylphosphanyl)-2-pyridylmethyl]propylaminomethyl}anthracene(872104-47-7)

Safety Data

• Hazardous Substances Data: 872104-47-7(Hazardous Substances Data)

Upstream product

• 63763-79-1 2-chloro-6-(bromomethyl)pyridine 
• 829-85-6 diphenylphosphane 

Relevant articles and documents

Synthesis, structure and spectroscopic properties of novel 9,10-bis{[6-(diphenylphosphanyl)-2-pyridylmethyl]propylaminomethyl} anthracene-bridged group 11 metal (M = CuI and AgI) dinuclear complexes

Dinuclear complexes [M2(μ-BPNNAn)]X2 (M = Cu I, X = ClO4- 1, 1X = BF4- 2; M = AgI, X = BF4- 3, X = ClO 4- 4) have been prepared by treating 9,10-bis{[6- (diphenylphosphanyl)-2-pyridylmethyl]propylaminomethyl}anthracene (BPNNAn) with M(CH3CN)4X in CH2Cl2. The structures of complexes 1, 2 and 3 have been determined by single-crystal X-ray diffraction studies. In the complexes, BPNNAn acts as a chelating ligand and two metal ions riding on two bridgehead carbon atoms in the anthracene group leads to the deformation of the anthracenyl ring. The Cu-Arene charge transfer interaction is observed from the nonfluorescent emission of Cu complex 1, while the Ag complex 3 exhibits dual emission at high concentrations in a CH 2Cl2 solution. Wiley-VCH Verlag GmbH & Co. KGaA, 2005.