87215-41-6

Basic information

• Product Name: Glycine, N-[1-[1-[(1,1-dimethylethoxy)carbonyl]-L-prolyl]-L-prolyl]-, phenylmethyl ester
• CAS NO: 87215-41-6
• Molecular Formula: C24H33N3O6
• Molecular Weight: 459.543
• Mol File: 87215-41-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Glycine, N-[1-[1-[(1,1-dimethylethoxy)carbonyl]-L-prolyl]-L-prolyl]-, phenylmethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Glycine, N-[1-[1-[(1,1-dimethylethoxy)carbonyl]-L-prolyl]-L-prolyl]-, phenylmethyl ester(87215-41-6)
• EPA Substance Registry System: Glycine, N-[1-[1-[(1,1-dimethylethoxy)carbonyl]-L-prolyl]-L-prolyl]-, phenylmethyl ester(87215-41-6)

Safety Data

• Hazardous Substances Data: 87215-41-6(Hazardous Substances Data)

Upstream product

• 15761-39-4 1-(tert-butoxycarbonyl)-L-proline 
• 16652-71-4 benzyl (2S)-2-pyrrolidinecarboxylate hydrochloride 
• 1738-76-7 glycine benzyl ester p-toluenesulfonic acid salt 
• 15401-08-8 N-tert-butoxycarbonyl-L-prolyl-L-proline 

Downstream Products

• 90315-71-2 N-(benzyloxycarbonyl)valylisoleucylphenylalanylprolylprolylglycyl-N^G-nitroarginine benzyl ester 
• 90315-39-2 [((S)-1-{(S)-1-[(S)-2-({(S)-1-[(S)-2-((S)-2-Benzyloxycarbonylamino-3-methyl-butyrylamino)-3-(4-hydroxy-phenyl)-propionyl]-pyrrolidine-2-carbonyl}-amino)-3-phenyl-propionyl]-pyrrolidine-2-carbonyl}-pyrrolidine-2-carbonyl)-amino]-acetic acid benzyl ester 
• 90315-40-5 [((S)-1-{(S)-1-[(S)-2-({(S)-1-[(S)-2-((S)-2-Benzyloxycarbonylamino-3-methyl-butyrylamino)-3-(4-hydroxy-phenyl)-propionyl]-pyrrolidine-2-carbonyl}-amino)-3-phenyl-propionyl]-pyrrolidine-2-carbonyl}-pyrrolidine-2-carbonyl)-amino]-acetic acid 
• 90315-70-1 N-(benzyloxycarbonyl)valylisoleucylphenylalanylprolylprolylglycine 
• 90315-52-9 C₆₅H₈₂N₁₀O₁₄ 
• 113727-10-9 Glycyl-L-isoleucin-benzylester 
• 90315-69-8 N-(benzyloxycarbonyl)valylisoleucylphenylalanylprolylprolylglycine benzyl ester 

Relevant articles and documents

Synthesis of novel all-cis-functionalized cyclopropane template-assembled collagen models

An all-cis-functionalized cyclopropane template to connect the three peptide chains in a collagen model is designed. Stereoselective synthesis of cyclopropane-assembled collagen-model 2b with the minimum unit of Gly-Pro-Pro is based on a novel 1-seleno-2-silylethene [2 + 1] cycloaddition strategy. Reaction of the 1-seleno-2-silylethene 4 with triester-substituted olefin 5 in the presence of ZnI2 gives [2 + 1] cycloadduct 6 stereoselectively. Cyclopropane 6 is selectively transformed into triol 10 in four steps. The reaction of 10 and three equivalents ofN-Boc-Pro-Pro-Gly-OH in the presence of WSC-DMAP and subsequent deprotection with TFA gives 2b.

STUDIES OF BITTER PEPTIDES FROM CASEIN HYDROLYZATE - VII. BITTERNESS OF THE RETRO-BPIa (VAL-ILE-PHE-PRO-PRO-GLY-ARG) AND ITS FRAGMENTS.

To explain the bitter taste exhibited by BPIa (Arg-Gly-Pro-Pro-Phe-Ile-Val) which was isolated from casein hydrolyzate, the authors propose the following requirement: its characteristic spatial structure: the basic moiety in the N-terminal and the hydroph