872164-44-8Relevant articles and documents
First examples of intramolecular addition of primary amidyl radicals to olefins
Gaudreault, Philippe,Drouin, Christian,Lessard, Jean
, p. 543 - 545 (2005)
The first examples of intramolecular addition of primary amidyl radicals to olefins are described. Amidyl radicals were generated from N-(phenylthio)amides in refluxing benzene using a catalytic amount of 2,2′- azobis(isobutyronitrile) (5 mol%) and tributyltin hydride (sim;2.2 equiv.). The resulting yields of cyclic products ranged from 63% to 85%.