872168-01-9

Basic information

• Product Name: (2S,3R,4R,SR)-methyl 5-(p-tolylsulfinyl)-2,3-bis(benzyloxy)-4-hydroxypentanoate
• Synonyms: (2S,3R,4R,SR)-methyl 5-(p-tolylsulfinyl)-2,3-bis(benzyloxy)-4-hydroxypentanoate
• CAS NO: 872168-01-9
• Molecular Weight: 482.598
• Mol File: 872168-01-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2S,3R,4R,SR)-methyl 5-(p-tolylsulfinyl)-2,3-bis(benzyloxy)-4-hydroxypentanoate(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3R,4R,SR)-methyl 5-(p-tolylsulfinyl)-2,3-bis(benzyloxy)-4-hydroxypentanoate(872168-01-9)
• EPA Substance Registry System: (2S,3R,4R,SR)-methyl 5-(p-tolylsulfinyl)-2,3-bis(benzyloxy)-4-hydroxypentanoate(872168-01-9)

Safety Data

• Hazardous Substances Data: 872168-01-9(Hazardous Substances Data)

Upstream product

• 872167-99-2 (2S,3S,SR)-methyl 5-(p-tolylsulfinyl)-2,3-bis(benzyloxy)-4-oxopentanoate 
• 100-39-0 benzyl bromide 
• 13171-64-7 Dimethyl D-tartrate 
• 195874-05-6 (2S,3S)-dimethyl 2,3-bis(benzyloxy)succinate 
• 81927-55-1 O-benzyl 2,2,2-trichloroacetimidate 
• 1519-39-7 (R)-methyl p-tolyl sulfoxide 

Downstream Products

• 872168-02-0 (3S,4S,5R,SR)-5-[(p-tolylsulfinyl)methyl]-3,4-bis(benzyloxy)-dihydrofuran-2-one 
• 1053654-41-3 (2S,3R,4R,SR)-2,3-bis-benzyloxy-4-hydroxy-1-phenyl-5-(p-tolylsulfinyl)-pentan-1-one 

Relevant articles and documents

The effect of sulfoxides on the stereoselective construction of tetrahydrofurans: Total synthesis of (+)-goniothalesdiol

Good to excellent stereoselectivities were achieved in the reductive cyclization (with Et3SiH/trimethylsilyl trifluoromethanesulfonate (TMSOTf)) of enantiopure hydroxy sulfinyl ketones en route to 2,5-cis-disubstituted tetrahydrofuran skeletons