872221-85-7Relevant articles and documents
Cyclotrimerization approach to unnatural structural modifications of pancratistatin and other amaryllidaceae constituents - Synthesis and biological evaluation
Hudlicky, Tomas,Moser, Michael,Banfield, Scott C.,Rinner, Uwe,Chapuis, Jean-Charles,Pettit, George R.
, p. 1313 - 1337 (2006)
The phenanthridone core of pancratistatin lacking all aromatic oxygenation was prepared by cyclotrimerization of acetylene-containing scaffolds 30 and 41, reflecting the natural and the C-1 epi configuration, respectively, of the amino inositol moiety. Th
Cyclotrimerization strategy toward analogues of amaryllidaceae constituents. Synthesis of deoxygenated pancratistatin core
Moser, Michael,Sun, Xuetong,Hudlicky, Tomas
, p. 5669 - 5672 (2007/10/03)
(Chemical Equation Presented) A derivative of pancratistatin having no oxygenation in the aromatic ring was synthesized by a new strategy based on the cobalt-catalyzed cyclotrimerization of acetylenes as a prelude to diversity-oriented synthesis of furthe