87228-35-1Relevant academic research and scientific papers
The high-temperature alicyclic ring contraction of 1,1-dichloroperfluorotetralin and the alicyclic ring opening of 1,1-dichloroperfluorobenzocyclobutene
Karpov, Victor M.,Mezhenkova, Tatyana V.,Platonov, Vyacheslav E.
, p. 714 - 717 (2008/03/13)
The pyrolysis of 1,1-dichloroperfluorotetralin (4) in a stream of argon gives a mixture contained perfluoro-1-methyleneindan (1), perfluoro-3-methylindene (6), 1,1-dichloroperfluoroindan (2) and perfluoroindene (7), while copyrolysis of tetralin 4 with CH
THERMOLYTIC REACTIONS OF POLYFLUOROORGANIC COMPOUNDS, PART XXVII. INTERACTION OF 1,1-DICHLOROPOLYFLUOROINDANES WITH HALOFORMS
Karpov, V. M.,Platonov, V. E.,Chuikov, I. P.,Yakobson, G. G.
, p. 459 - 474 (2007/10/02)
A number of polyfluoro-1-methyleneindanes have been obtained by copyrolysis of 1,1-dichloropolyfluoroindanes with CF2=CF2, CHClF2, CHCl2F, CHCl3.A possibility is shown for the reaction of 1,1-dichloroctafluoroindan with CHClF2 to proceed by way of difluorocarbene insertion into the C - Cl bond of the benzylic position of this indan, with subsequent dechlorination of the insertion product.
