87228-37-3Relevant academic research and scientific papers
THERMOLYTIC REACTIONS OF POLYFLUOROORGANIC COMPOUNDS, PART XXVII. INTERACTION OF 1,1-DICHLOROPOLYFLUOROINDANES WITH HALOFORMS
Karpov, V. M.,Platonov, V. E.,Chuikov, I. P.,Yakobson, G. G.
, p. 459 - 474 (1983)
A number of polyfluoro-1-methyleneindanes have been obtained by copyrolysis of 1,1-dichloropolyfluoroindanes with CF2=CF2, CHClF2, CHCl2F, CHCl3.A possibility is shown for the reaction of 1,1-dichloroctafluoroindan with CHClF2 to proceed by way of difluorocarbene insertion into the C - Cl bond of the benzylic position of this indan, with subsequent dechlorination of the insertion product.
