Journal of Fluorine Chemistry p. 459 - 474 (1983)
Update date:2022-07-29
Topics:
Karpov, V. M.
Platonov, V. E.
Chuikov, I. P.
Yakobson, G. G.
A number of polyfluoro-1-methyleneindanes have been obtained by copyrolysis of 1,1-dichloropolyfluoroindanes with CF2=CF2, CHClF2, CHCl2F, CHCl3.A possibility is shown for the reaction of 1,1-dichloroctafluoroindan with CHClF2 to proceed by way of difluorocarbene insertion into the C - Cl bond of the benzylic position of this indan, with subsequent dechlorination of the insertion product.
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Doi:10.1002/chem.200500478
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