87239-89-2Relevant academic research and scientific papers
Synthesis and Properties of 5,10,15,20-Tetrakis(3,5-di-t-butyl-2-nitrophenyl)porphyrin: Conformational Stabilities of the Respective Atropisomers and Oxygenation Capabilities of the Iron(III) and Manganese(III) Complexes
Miyamoto, T. Ken,Takagi, Shigeru,Hasegawa, Tai,Tsuzuki, Seizi,Takahashi, Eitaro,et al.
, p. 1649 - 1660 (2007/10/02)
The synthesis and properties of new, bulky atropisomeric porphyrins are described.Four atropisomers of 5,10,15,20-tetrakis(3,5-di-t-butyl-2-nitrophenyl)porphyrins has been easily separated and purified by column chromatography.The isomers all have differe
STERICALLY BULKY PORPHYRINS: THE ATROPISOMERS OF TETRAKIS(3,5-DI-TERT-BUTYL-2-NITROPHENYL)PORPHYRIN AND THEIR IRON(III) COMPLEXES
Miyamoto, T. Ken,Hasegawa, Tai,Takagi, Shigeru,Sasaki, Yukiyoshi
, p. 1181 - 1184 (2007/10/02)
A new "bis pocket" porphyrin has been prepared and characterized.Its four geometric isomers (atropisomers) have been separated by chromatography.Each isomer has relatively high conformational stability to light and prolonged heating.Practical utility of t
