87243-93-4

Basic information

• Product Name: 1H-Phosphole, 2,5-dihydro-1-hydroxy-3-methyl-, 1-oxide
• Synonyms: 1H-Phosphole,2,5-dihydro-1-hydroxy-3-methyl-,1-oxide;3-methyl-2,5-dihydro-1H-phosphol-1-ol 1-oxide;1-hydroxy-3-phospholene 1-oxide;1-hydroxy-3-methyl-2,5-dihydro-1H-phosphole oxide;1-hydroxy-3-methyl-3-phospholene 1-oxide;1-hydroxy-3-methyl-2,5-dihydro-1H-phosphole 1-oxide;1-hydroxy-3-methyl-3-phospholene oxide
• CAS NO: 87243-93-4
• Molecular Formula: C5H9O2P
• Molecular Weight: 132.099
• Mol File: 87243-93-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1H-Phosphole, 2,5-dihydro-1-hydroxy-3-methyl-, 1-oxide(CAS DataBase Reference)
• NIST Chemistry Reference: 1H-Phosphole, 2,5-dihydro-1-hydroxy-3-methyl-, 1-oxide(87243-93-4)
• EPA Substance Registry System: 1H-Phosphole, 2,5-dihydro-1-hydroxy-3-methyl-, 1-oxide(87243-93-4)

Safety Data

• Hazardous Substances Data: 87243-93-4(Hazardous Substances Data)

Upstream product

• 695-59-0 2,5-dihydro-1-methoxy-3-methyl-1H-phosphole 1-oxide 
• 697-31-4 1-ethoxy-3-methyl-2,5-dihydro-1H-phosphole 1-oxide 

Downstream Products

• 183163-60-2 1-(2,4-Di-tert-butyl-6-methyl-phenyl)-3-methyl-2,5-dihydro-1H-phosphole 
• 182359-52-0 1-(2,4-Di-tert-butyl-6-methyl-phenyl)-3-methyl-2,5-dihydro-phosphole 1-oxide 
• 183163-62-4 1-(2',4'-di-tert-butyl-6'-methylphenyl)-3-methylphosphole 
• 183163-63-5 3,4-Dibromo-1-(2,4-di-tert-butyl-6-methyl-phenyl)-3-methyl-phospholane 
• 432522-11-7 1-(4'-methoxyphenyl)-3-methyl-2-phospholene 1-oxide 
• 7529-24-0 1-ethyl-3-methyl-2,5-dihydro-1H-phosphole oxide 
• 695-59-0 2,5-dihydro-1-methoxy-3-methyl-1H-phosphole 1-oxide 
• 2921-68-8 1-(2-phenylethoxy)-3-methyl-3-phospholene 1-oxide 
• 2921-67-7 1-benzyloxy-3-methyl-3-phospholene 1-oxide 
• 3858-23-9 1-cyclohexyloxy-3-methyl-3-phospholene 1-oxide 
• 1207893-85-3 1-[(1R,2S,5R)-menthyloxy]-3-methyl-3-phospholene-1-oxide 
• 2921-66-6 1-(n-pentyloxy)-3-methyl-3-phospholene 1-oxide 
• 1428266-08-3 1-(benzylamino)-3-methyl-2,5-dihydro-1H-phosphole-1-oxide 
• 1428266-07-2 1-(cyclohexylamino)-3-methyl-2,5-dihydro-1H-phosphole-1-oxide 

Relevant articles and documents

Hydrolysis and alcoholysis of phosphinates and phosphonates

Phosphinic and phosphonic acids useful intermediates and biologically active compounds may be prepared from their esters: phosphinates and phosphonates, respectively, by acid-catalyzed hydrolysis either on conventional heating or on MW irradiation. The transesterification of alkyl phosphinates took place only in the presence of suitable ionic liquids as the catalysts. In the cases of phenylphosphonates, depending on the nature of the ionic liquid, the formation of the ester was accompanied by the fission of the C–O bond.