87273-91-4Relevant articles and documents
ARYL REARRANGEMENT ON THE PHOTOLYSIS OF 2-ARYL-2-ETHOXY-2-PHENYLETHYL CABALOXIME.
Tada,Inoue,Okabe
, p. 1420 - 1423 (2007/10/02)
The photolysis of 2-aryl-2-ethoxy-2-phenylethyl cobaloxime followed by hydrolysis gave two kinds of substituted 1,2-diphenylethanones arising via phenyl or substituted-phenyl migration. The substituent effect on the aryl rearrangement is similar to that on the reported neophyl rearrangement, and the rearrangement takes place by a radical mechanism without the deep involvement of cobaloxine(II).