87282-03-9

Basic information

• Product Name: 3,5-dimethyl-N-phenylbenzamide
• Synonyms: 3,5-dimethyl-N-phenylbenzamide
• CAS NO: 87282-03-9
• Molecular Formula: C₁₅H₁₅NO
• Molecular Weight: 225.2857
• Mol File: 87282-03-9.mol
• Article Data: 13

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3,5-dimethyl-N-phenylbenzamide(CAS DataBase Reference)
• NIST Chemistry Reference: 3,5-dimethyl-N-phenylbenzamide(87282-03-9)
• EPA Substance Registry System: 3,5-dimethyl-N-phenylbenzamide(87282-03-9)

Safety Data

• Hazardous Substances Data: 87282-03-9(Hazardous Substances Data)

Upstream product

• 694-59-7 pyridine N-oxide 
• 87281-96-7 3,5-Dimethyl-N-phenyl-benzimidoyl chloride 
• 103-71-9 phenyl isocyanate 
• 611-01-8 2,4-dimethyl-benzoic acid 
• 1227476-15-4 Azobenzene 
• 108-67-8 1,3,5-trimethyl-benzene 
• 201230-82-2 carbon monoxide 
• 62-53-3 aniline 
• 172975-69-8 3,5-dimethylphenyl boronic acid 
• 98-80-6 phenylboronic acid 
• 3422-02-4 N-(benzyloxycarbonyl)aniline 
• 3422-01-3 tert-butyl phenylcarbamate 
• 18992-89-7 allyl N-phenylcarbamate 
• 287935-95-9 (3,5-dimethylphenyl)trimethoxysilane 

Relevant articles and documents

Visible-Light-Promoted Iron-Catalyzed N-Arylation of Dioxazolones with Arylboronic Acids

A visible-light-promoted and simple iron salt-catalyzed N-arylation was achieved efficiently under external photosensitizer-free conditions. Arylboronic acids and bench-stable dioxazolones were used for this cross-coupling reaction. This reaction features high reactivity, wide substrate scope, good functional group tolerance, simple operation procedure, and mild reaction conditions. Preliminary mechanistic investigations were conducted to support a radical pathway. This method may contribute to shift the paradigm of iron-catalyzed C-N bond construction and nitrene transfer chemistry.

Synthesis of Amides by Mild Palladium-Catalyzed Aminocarbonylation of Arylsilanes with Amines Enabled by Copper(II) Fluoride

A general Pd-catalyzed synthesis of amides by oxidative aminocarbonylation of arylsilanes under mild conditions was accomplished for the first time. The reaction is promoted by a commercially available copper(II) fluoride, which acts as a dual silane activator and mild oxidant, enabling highly efficient aminocarbonylation of versatile arylsilanes at atmospheric CO pressure. The reaction is tolerant of a wide range of arylsilanes and various sensitive halide functional groups as well as a broad scope of amines are compatible with this oxidative process using cheap CO. A significant aspect involves the increased efficiency by the catalyst system. The reaction represents a segue into the powerful Pd-catalyzed oxidative transformations of organosilanes.

Interpositus substituted N-aryl benzoyl amines one-step synthesis method of the compound

The invention discloses a one-step synthetic method of meta-substituted N-arylbenzamide compounds. Transition metal ruthenium is used as a catalyst, and the meta-substituted N-arylbenzamide compounds are synthesized in one step through carboxy-based o-C-H functionalization/ decarboxylation coupling reaction of aromatic acid and phenyl isocyanate compounds. The method has the advantages that the raw materials are simple and readily available, the catalyst is cheap, the reaction operation is simple, the utilization rate of atoms is high, the method is environment-friendly and the like.