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Metal Template Reactions. XV. The Scope of Macrocyclic Metal Complex Formation from Malonamido Dicarbonyl Precursors
Black, David St. C.,Blatt, Harry,Vanderzalm, Corrie H. Bos,Liepa, Andris J.
, p. 1133 - 1140 (2007/10/02)
The malonamido dicarbonyl compounds (4)-(6), (8), (13), (15) and (16) have been prepared as potential precursors of macrocyclic nickel(II) complexes.Such complexes could only be formed succesfully from the dimethylmalonyl derivative (4).The benzylidene-substituted benzophenone derivatives (15) and (16) underwent a metal-promoted pinacol reaction to yield compounds (17) and (18) containing an 11-membered ring.
