87301-05-1Relevant academic research and scientific papers
STERIC EFFECTS OF PHOSPHORUS LIGANDS: cis/trans DISTRIBUTIONS OF W(CO)4L2 PRODUCTS
Ounapu, Lois M.,Mosbo, John A.,Risley, John M.,Storhoff, Bruce N.
, p. 337 - 342 (2007/10/02)
The cis/trans product distribution in the reaction of phosphines with W(CO)4(Me2N(CH2)3NMe2) depends on ligand size; the smaller the ligand the greater the cis/trans ratio.The ratios range from 2.9 to 0 for PPh2Me and P(o-Tol)3, respectively.
