36351-36-7

Upstream product

• 13283-01-7 tungsten(VI) chloride 
• 1486-28-8 diphenyl(methyl)phosphine 
• 1333-74-0 hydrogen 

Downstream Products

• 66518-96-5 {WH₅(P(C₆H₅)2CH₃)4}⁽¹⁺⁾*Cl^(1-)={WH₅(P(CH₃)(C₆H₅)2)4}Cl 
• 110174-50-0 W(OC6H3Ph-η6-C6H5)H(PMePh2)2 
• 38900-82-2 edge-W(CO)3(PMePh₂)3 
• 38900-82-2 fac-W(CO)3(PMePh₂)3 
• 87301-05-1 W(CO)4(P(CH₃)(C₆H₅)2)2 

Relevant academic research and scientific papers

Hydrogenolysis of tetra(allyl)tungsten in the presence of tertiary phosphines: synthesis of tris(dmpm)tungsten (0)

Reaction of W(η3-C3H5)4 with PMe2Ph and Me2PCH2PMe2 (dmpm) under 1 atm of H2 in toluene at 110-120 deg C yielded WH4(PMe2Ph)4 and W(dmpm)3, respectively.Spectroscopic studies on the hydrogenolysis of W(η3-C3H5)4 in the presence of tertiary phosphines PEt3, PMePh2, and PPh3 were consistent with formation of the tungsten phosphine hydride complexes WH6(PEt3)3, WH4(PMePh2)4 and WH6(PPh3)3.W(η3-C3H5)4 has advantages over similar hydrogenolysis of WMe6 in that W(η3-C3H5)4 is considerably more thermally and air stable.Pyrolysis of WH4(PMePh2)4 at 400 deg C under a hydrogen flow yielded a shiny tungsten powder contaminated by hydrocarbon residues.Keywords: Tungsten; Phosphines; Hydrides; Hydrogenolysis; Hydrogenation