873077-87-3

Upstream product

• 557-34-6 zinc diacetate 
• 917-23-7 5,15,10,20-tetraphenylporphyrin 
• 5970-45-6 zinc(II) acetate dihydrate 

Downstream Products

• 873077-88-4 [meso-tetraphenyl-3-hydroxy-2-oxachlorinato]Zn(II) 

Relevant academic research and scientific papers

Tunable meso -tetraphenyl-alkyloxazolo-chlorins and -bacteriochlorins

Chemical equations presented. Alkyl-Grignard addition to meso-tetraphenylporpholactone generates monoalkyl- and gem-bis- alkyloxazolochlorins. Together with compounds made by further synthetic manipulations of these derivatives, a series of chlorin-type c

Oxazolochlorins 21. most efficient access to meso-tetraphenyl- And meso-tetrakis(pentafluorophenyl)porpholactones, and their zinc(II) and platinum(II) complexes

meso-Phenyl- and meso-pentafluorophenyl-porpholactones, their metal complexes, as well as porphyrinoids directly derived from them are useful in a number of technical and biomedical applications, and more uses are expected to be discovered. About a dozen

Catalysts and processes for producing aldehydes

Use of a unique supramolecular assembly of a tris-pyridylphosphine ligand and a metal centered porphyrin complex modified with a lactone functional group was shown to have improved selectivities to branched aldehydes via rhodium catalyzed hydroformylation of unsubstituted linear alpha olefins such as propylene and 1-octene. The addition of potassium salts was also shown to increase the activity of the lactone modified porphyrin-based catalyst while maintaining similar branched aldehyde selectivities for propylene hydroformylation.

Tuning the Porphyrin Building Block in Self-Assembled Cages for Branched-Selective Hydroformylation of Propene

Unprecedented regioselectivity to the branched aldehyde product in the hydroformylation of propene was attained on embedding a rhodium complex in supramolecular assembly L2, formed by coordination-driven self-assembly of tris(meta-pyridyl)phosphine and zinc(II) porpholactone. The design of cage L2 is based on the ligand-template approach, in which the ligand acts as a template for cage formation. Previously, first-generation cage L1, in which zinc(II) porphyrin units were utilized instead of porpholactones, was reported. Binding studies demonstrate that the association constant for the formation of second-generation cage L2 is nearly an order of magnitude higher than that of L1. This strengthened binding allows cage L2 to remain intact in polar and industrially relevant solvents. As a consequence, the unprecedented regioselectivity for branched aldehyde products can be maintained in polar and coordinating solvents by using the second-generation assembly.

Meso-arylporpholactones and their reduction products

The rational syntheses of meso-tetraaryl-3-oxo-2-oxaporphyrins 5, known as porpholactones, via MnO4--mediated oxidations of the corresponding meso-tetraaryl-2,3-dihydroxychlorins (7) is detailed. Since chlorin 7 is prepared from the parent porphyrin 1, this amounts to a 2-step replacement of a pyrrole moiety in 1 by an oxazolone moiety. The stepwise reduction of the porpholactone 5 results in the formation of chlorin analogues, meso-tetraaryl-3-hydroxy-2-oxachlorin (11) and meso-tetraaryl-2-oxachlorins (12). The reactivity of 11 with respect to nucleophilic substitution by O-, N-, and S-nucleophiles is described. The profound photophysical consequences of the formal replacement of a pyrrole with an oxazolone (porphyrin-like chromophore) or (substituted) oxazole moiety (chlorin-like chromophore with, for the parent oxazolochlorin 12, red-shifted Qx band with enhanced oscillator strengths) are detailed and rationalized on the basis of SAC-CI and MNDO-PSDCI molecular orbital theory calculations. The single crystal X-ray structures of the porpholactones point at a minor steric interaction between the carbonyl oxygen and the flanking phenyl group. The essentially planar structures of all chromophores in all oxidation states prove that the observed optical properties originate from the intrinsic electronic properties of the chromophores and are not subject to conformational modulation.