873222-80-1

Basic information

• Product Name: [Cu(3,3'-iminobis(N,N-dimethylpropylamine)(N-benzoylanthranilate)]ClO₄
• CAS NO: 873222-80-1
• Molecular Weight: 590.563
• Mol File: 873222-80-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Cu(3,3'-iminobis(N,N-dimethylpropylamine)(N-benzoylanthranilate)]ClO₄(CAS DataBase Reference)
• NIST Chemistry Reference: [Cu(3,3'-iminobis(N,N-dimethylpropylamine)(N-benzoylanthranilate)]ClO₄(873222-80-1)
• EPA Substance Registry System: [Cu(3,3'-iminobis(N,N-dimethylpropylamine)(N-benzoylanthranilate)]ClO₄(873222-80-1)

Safety Data

• Hazardous Substances Data: 873222-80-1(Hazardous Substances Data)

Upstream product

• 579-93-1 2-(Benzoylamino)benzoic Acid 
• 14057-91-1 tetrakis(acetonitrile)copper(I) perchlorate 
• 6711-48-4 N,N-bis-(3-dimethylaminopropyl)amine 

Relevant articles and documents

Copper-catalyzed oxygenation of 3-hydroxy-2-phenylquinolin-4(1H)-one: Synthesis, structure and spectral properties of [Cu(idpa)(N-baa)]ClO 4, [idpa = 3,3′-iminobis(N,N-dimethylpropylamine), N-baaH = N-benzoylanthranilic acid]

Reaction of one molar equivalent of 3,3′-iminobis(N,N- dimethylpropylamine (idpa)), N-benzoylanthranilic acid (N-baaH) and [Cu(CH 3CN)4](ClO4) in acetonitrile resulted in the formation of a stable ionic copper(II) complex without additional solvent coordination. The composition and molecular structure of [Cu(idpa)(N-baa)] ClO4 was fully determined by IR, UV-vis, and X-ray crystal analysis. The complex has a distorted square planar CuN3O core. The oxygenation of 3-hydroxy-2-phenylquinolin-4(1H)-one (QuinH2) using [Cu(idpa)(N-baa)]ClO4 as a catalyst results in the oxidative cleavage of the heterocyclic ring to give a N-benzoylanthranilic acid and CO as a mimic of quercetinase and 3-hydroxy-1,4-dihydroquinolin-4-one 2,4-dioxygenase action.