87324-21-8

Basic information

• Product Name: 1-(4-Bromo-phenyl)-6,6-dimethyl-2-phenyl-1,5,6,7-tetrahydro-indol-4-one oxime
• Synonyms: 1-(4-Bromo-phenyl)-6,6-dimethyl-2-phenyl-1,5,6,7-tetrahydro-indol-4-one oxime
• CAS NO: 87324-21-8
• Molecular Weight: 409.326
• Mol File: 87324-21-8.mol

Chemical Properties

• CAS DataBase Reference: 1-(4-Bromo-phenyl)-6,6-dimethyl-2-phenyl-1,5,6,7-tetrahydro-indol-4-one oxime(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(4-Bromo-phenyl)-6,6-dimethyl-2-phenyl-1,5,6,7-tetrahydro-indol-4-one oxime(87324-21-8)
• EPA Substance Registry System: 1-(4-Bromo-phenyl)-6,6-dimethyl-2-phenyl-1,5,6,7-tetrahydro-indol-4-one oxime(87324-21-8)

Safety Data

• Hazardous Substances Data: 87324-21-8(Hazardous Substances Data)

Upstream product

• 83558-08-1 1-(4-bromophenyl)-6, 6-dimethyl-2-phenyl-1,5,6,7-tetrahydro-4H-indol-4-one 

Downstream Products

• 87324-32-1 1-(4-Bromo-phenyl)-7,7-dimethyl-2-phenyl-5,6,7,8-tetrahydro-1H-pyrrolo[3,2-c]azepin-4-one 

Relevant articles and documents

Synthesis and spectral properties of the 1-aryl-2-phenyl-4-oxo-4,5,6,7-tetrahydroinodle oximes and of their Beckmann rearrangement products

Under Beckmann conditions the oximes of the 1-aryl-2-phenyl-4-oxo-4,5,6,7-tetrahydroindoles 2a-k are rearranged yielding as the sole product, 1-aryl-2-phenyl-4-oxo-1,4,5,6,7,8-hexahydropyrrolo[3,2-c]azepine 3a-k. The spectral data (ir, uv, ms) of these two classes of compounds are also discussed.