873297-79-1Relevant articles and documents
Modular bisphosphine ligands: Preparation and application in enantioselective catalytic reactions
G?k, Ya?ar,Karayi?it, ?lker ümit,G?k, Halil Zeki
, p. 44 - 50 (2017)
A set of six chiral modular C2-symmetric bisphosphine ligands have been synthesized in a straightforward manner through a two-step reaction from the corresponding diols with moderate yields. The applicability of these chiral ligands was evaluated in ruthenium(II)-catalyzed transfer hydrogenation reactions (up to >99% conversion) and palladium(0)-catalyzed enantioselective allylic substitution reactions (up to 70% chemical yield and 43% ee).