873313-18-9Relevant academic research and scientific papers
4-Functionally-substituted 3-heterylpyrazoles: XV. 3-Aryl(heteryl)-1- phenyl-4-pyrazolylmethylamines and heterocumulenes obtained therefrom
Bratenko,Panimarchuk,Mel'nichenko,Vovk
, p. 238 - 242 (2007/10/03)
By reduction of 3-aryl(heteryl)-1-phenyl-4-azidomethyl-pyrazoles in the presence of Raney nickel or by hydrazinolysis of N-[3-aryl(heteryl)-1-phenyl-4- pyrazolylmethyl]phthalimides 4-pyrazolylmethylamines were obtained that in reaction with bis(trichloromethyl) carbonate afforded 3-aryl-(heteryl)-1-phenyl- 4-pyrazolylmethyl isocyanates, and with carbon disulfide furnished 3-aryl-(heteryl)-1-phenyl-4-pyrazolylmethyl isothiocyanates. 2005 Pleiades Publishing, Inc.
Functionally substituted 3-heterylpyrazoles: IX. 3-Aryl(heteryl)-4-mercapto(thiocyanato, isothiocyanato)-methylpyrazoles
Bratenko,Chornous,Vovk
, p. 595 - 598 (2007/10/03)
By reaction of 3-aryl(heteryl)-4-chloromethylpyrazoles with thiourea and sodium thiocyanate respectively 3-aryl(heteryl)-4-mercaptomethylpyrazoles and 3-aryl(heteryl)-thiocyanatomethylpyrazoles were obtained. The latter were subjected to thermal isomerization into 3-aryl(heteryl)-isothiocyanatomethylpyrazoles.
