873386-13-1

Basic information

• Product Name: acetic acid-[2-(4-chloro-phenoxy)-anilide]
• Synonyms: acetic acid-[2-(4-chloro-phenoxy)-anilide]
• CAS NO: 873386-13-1
• Molecular Weight: 261.708
• Mol File: 873386-13-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: acetic acid-[2-(4-chloro-phenoxy)-anilide](CAS DataBase Reference)
• NIST Chemistry Reference: acetic acid-[2-(4-chloro-phenoxy)-anilide](873386-13-1)
• EPA Substance Registry System: acetic acid-[2-(4-chloro-phenoxy)-anilide](873386-13-1)

Safety Data

• Hazardous Substances Data: 873386-13-1(Hazardous Substances Data)

Upstream product

• 2770-11-8 2-(4-chlorophenoxy)aniline 
• 75-36-5 acetyl chloride 
• 106-48-9 4-chloro-phenol 
• 88-73-3 2-Chloronitrobenzene 
• 1121-74-0 potassium 4-chlorophenoxide 
• 2216-12-8 1-nitro-2-phenoxy-benzene 
• 108-24-7 acetic anhydride 

Downstream Products

• 873977-72-1 acetic acid-[2-(4-chloro-phenoxy)-4-nitro-anilide] 

Relevant articles and documents

Access to Chiral Seven-Member Cyclic Amines via Rh-Catalyzed Asymmetric Hydrogenation

A highly efficient asymmetric hydrogenation of azepine/oxazepine-type seven-member cyclic imine hydrochlorides was successfully developed using Rh/bisphosphine-thiourea ligand ZhaoPhos, affording various chiral seven-member cyclic amines with full conversions, high yields, and excellent enantioselectivities (up to 96% yield, >99% ee). Additionally, this asymmetric hydrogenation can proceed well on gram scale with excellent ee value. Moreover, control experimental results displayed that the anion-bonding interaction between the chloride ion of the substrate and thiourea motif of the ZhaoPhos played an important role to obtain excellent enantioselectivity.