873547-13-8

Basic information

• Product Name: methyl (E)-2-[4,5-dihydrofuran-2(3H)-ylidene]-2-(4-methoxyphenyl)acetate
• Synonyms: methyl (E)-2-[4,5-dihydrofuran-2(3H)-ylidene]-2-(4-methoxyphenyl)acetate
• CAS NO: 873547-13-8
• Molecular Weight: 248.279
• Mol File: 873547-13-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl (E)-2-[4,5-dihydrofuran-2(3H)-ylidene]-2-(4-methoxyphenyl)acetate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (E)-2-[4,5-dihydrofuran-2(3H)-ylidene]-2-(4-methoxyphenyl)acetate(873547-13-8)
• EPA Substance Registry System: methyl (E)-2-[4,5-dihydrofuran-2(3H)-ylidene]-2-(4-methoxyphenyl)acetate(873547-13-8)

Safety Data

• Hazardous Substances Data: 873547-13-8(Hazardous Substances Data)

Upstream product

• 52196-15-3 E isomer of methyl α-(tetrahydro-2-furylidene)acetate 
• 5720-07-0 4-methoxyphenylboronic acid 
• 805228-92-6 methyl (Z)-2-bromo-2-[4,5-dihydrofuran-2(3H)-ylidene]acetate 

Relevant articles and documents

Synthesis of functionalized 2-alkylidene-tetrahydrofurans based on a [3+2] cyclization/bromination/palladium(0) cross-coupling strategy

The bromination of 2-alkylidene-tetrahydrofurans and 2-alkylidene- pyrrolidines - readily available through one-pot [3+2] cyclization reactions - afforded 2-alkylidene-1′-bromotetrahydrofurans, 2-alkylidene-3- bromotetrahydrofurans and 2-alkylidene-1′,3-dibromotetrahydrofurans and their pyrrolidine counterparts. 2-Alkylidene-1′-bromotetrahydrofurans were functionalized by performing Suzuki and Heck reactions. 2-Alkylidene-1′, 3-dibromotetrahydrofurans were successfully employed in novel double-Suzuki reactions. Wiley-VCH Verlag GmbH & Co. KGaA, 2005.