87357-89-9Relevant academic research and scientific papers
A highly stereoselective synthesis of (+)-olivin, the aglycon of olivomycin A
Roush,Michaelides,Tai,Lesur,Chong,Harris
, p. 2984 - 2995 (2007/10/02)
The first total synthesis of (+)-olivin (1), the naturally occurring enantiomer of the aglycon of olivomycin A, is described. The synthesis is highly stereoselective, featuring the reaction of (γ-methoxyallyl)boronate 21 with chiral aldehyde 17 and the ad
Stereochemistry of Vinyl Cuprate Additions to Carbohydrate-Derived Enones and α,β-Unsaturated Esters
Roush, William R.,Lesur, Brigitte M.
, p. 2231 - 2234 (2007/10/02)
Vinylic cuprate reagents add with excellent diastereoselectivity (>10:1) to carbohydrate derived enones and α,β-unsaturated esters.The stereochemical outcome of these transformations is consistent with a Felkin-type addition pathway.
