87374-36-5

Upstream product

• 87357-83-3 (4S,5R)-4-((E)-(1R,2S)-1-Benzyloxy-2-methoxy-5-oxo-hex-3-enyl)-5-methyl-[1,3]dioxolan-2-one 
• 87357-84-4 (4S,5R)-4-((Z)-(1R,2S)-1-Benzyloxy-2-methoxy-5-oxo-hex-3-enyl)-5-methyl-[1,3]dioxolan-2-one 
• 87357-82-2 4(R),5(S),6(R),7(S),8(R)-6-(Benzyloxy)-5-methoxy-7,8-dihydroxy-4-vinyl-nonan-2-one 7,8-carbonate 
• 120264-46-2 D-Galacto-6-(benzyloxy)-7,8-dihydroxy-5-methoxynon-3(E)-en-2-one 7,8-cyclohexyl ketal 
• 120264-45-1 (2S,3R)-2-((1R,2S)-1-Benzyloxy-2-methoxy-but-3-enyl)-3-methyl-1,4-dioxa-spiro[4.5]decane 
• 87256-55-1 D-Galacto-3-methoxyhept-1-ene-4,5,6-triol 5,6-cyclohexyl ketal 
• 87305-35-9 L-4-deoxythreose cyclohexyl ketal 
• 120264-49-5 4(R),5(S),6(R),7(S),8(R)-6-(Benzyloxy)-5-methoxy-7,8-dihydroxy-4-vinylnonan-2-one 7,8-cyclohexyl ketal 
• 87357-89-9 (4R,5S,6S,7S,8R)-6-Benzyloxy-7,8-dihydroxy-5-methoxy-4-vinyl-nonan-2-one 

Relevant academic research and scientific papers

A highly stereoselective synthesis of (+)-olivin, the aglycon of olivomycin A

The first total synthesis of (+)-olivin (1), the naturally occurring enantiomer of the aglycon of olivomycin A, is described. The synthesis is highly stereoselective, featuring the reaction of (γ-methoxyallyl)boronate 21 with chiral aldehyde 17 and the ad