87361-72-6Relevant academic research and scientific papers
Pd(II)-catalyzed asymmetric fluorination of α-aryl-α- cyanophosphonates with the aid of 2,6-lutidine
Moriya, Ken-Ichi,Hamashima, Yoshitaka,Sodeoka, Mikiko
, p. 1139 - 1142 (2008/03/13)
We describe herein the catalytic asymmetric fluorination of α-cyanophosphonates using chiral Pd(H)-bisphosphine complexes. While metal complexes failed to promote the reaction alone, a reaction system involving Pd(II) and organic base such as 2,6-lutidine
Arylation of α-substituted diethyl methylphosphonates with π-complexes of haloarenes
Artamkina,Sazonov,Beletskaya
, p. 76 - 86 (2007/10/03)
Nucleophilic aromatic substitution of halogen in neutral and cationic π-complexes of haloarenes η6-(ArF)Cr(CO)3 and [η6-(ArHlg)FeCp]+[PF6]- (Hlg = F, Cl) by carbanions derived from α-substi
Arylation of phosphoryl-stabilized carbanions with metal π-complexes of aryl chlorides and fluorides
Artamkina, Galina A.,Sazonov, Petr K.,Beletskaya, Irina P.
, p. 4385 - 4387 (2007/10/03)
The nucleophilic aromatic substitution of halogen in metal arene π-complexes η6-(ArF)Cr(CO)3 and [η6-(ArHal)FeCp]+[PF6]- (Hal = F,Cl) with phosphoryl-stabilized carbanions ZCH2P(
A NEW FACILE SYNTHESIS OF DIETHYL 1-ARYL-1-CYANOMETHANEPHOSPHONATES
Kim, Dae Young,Oh, Dong Young
, p. 953 - 958 (2007/10/02)
Titanium(IV) chloride-cytalyzed addition of diethyl trimethylsilyl phosphite to β-nitrostyrenes affords α-phosphoryl nitronates which, on treatment with low valent titanium in situ generated from titanium(IV) and zinc, are smoothly converted to 1-aryl-1-cyanomethanephosphonates in good yields.
