873800-84-1Relevant articles and documents
Silicon-initiated carbonylative carbotricyclization and [2+2+2+1] cycloaddition of enediynes catalyzed by rhodium complexes
Bennacer, Bibia,Fujiwara, Masaki,Lee, Seung-Yub,Ojima, Iwao
, p. 17756 - 17767 (2007/10/03)
The reaction of dodec-11-ene-1,6-diynes or their heteroatom congeners with a hydrosilane catalyzed by Rh(acac)(CO)2 at ambient temperature and pressure of CO gives the corresponding fused 5-7-5 tricyclic products, 5-oxo-1,3a,4,5,7,9-hexahydro-3