87384-87-0

Basic information

• Product Name: (E)-(3,3,4,4,5,5,5-heptafluoropent-1-enyl)benzene
• Synonyms: (E)-(3,3,4,4,5,5,5-heptafluoropent-1-enyl)benzene
• CAS NO: 87384-87-0
• Molecular Weight: 272.165
• Mol File: 87384-87-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (E)-(3,3,4,4,5,5,5-heptafluoropent-1-enyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-(3,3,4,4,5,5,5-heptafluoropent-1-enyl)benzene(87384-87-0)
• EPA Substance Registry System: (E)-(3,3,4,4,5,5,5-heptafluoropent-1-enyl)benzene(87384-87-0)

Safety Data

• Hazardous Substances Data: 87384-87-0(Hazardous Substances Data)

Upstream product

• 100-42-5 styrene 
• 754-34-7 1,1,1,2,2,3,3-heptafluoro-3-iodo-propane 
• 1199-95-7 1-(trimethylstannyl)-2-phenylethyne 
• 7422-28-8 trimethylstannylstyrene 
• 99930-45-7 2,2,3,3,4,4,4-Heptafluoro-butyric acid 3,3,4,4,5,5,5-heptafluoro-1-phenyl-pentyl ester 
• 7422-28-8 (Z)-1-Phenyl-2-(trimethylstannyl)aethen 
• 99930-54-8 3,3,4,4,5,5,5-heptafluoro-1-phenyl-1-pentanol 
• 336-64-1 bis(heptafluorobutyryl) peroxide 

Relevant articles and documents

Practical Photocatalytic Trifluoromethylation and Hydrotrifluoromethylation of Styrenes in Batch and Flow

Styrenes represent a challenging class of substrates for current radical trifluoromethylation and hydrotrifluoromethylation methods due to a myriad of potential side reactions. Herein, we describe the development of mild, selective and broadly applicable photocatalytic trifluoromethylation and hydrotrifluoromethylation protocols for these challenging substrates. The methods use fac-Ir(ppy)3, visible light and inexpensive CF3I and can be applied to a diverse set of vinylarene substrates. The use of continuous-flow photochemical reaction conditions allowed to reduce the reaction time and increase the reaction selectivity.

HEPTAFLUOROPROPYLATION OF ELECTRON-RICH OLEFINS WITH BIS(HEPTAFLUOROBUTYRIL) PEROXIDE

Bis(heptafluorobutyril) peroxide reacted with electron-rich olefins to give the adducts of C3F7CO2 and C3F7 groups in good yields.The peroxide should be the useful reagent for the introduction of heptafluoropropyl moiety into olefins.