873958-71-5Relevant academic research and scientific papers
Sulfur dioxide insertion into the Co-C bond in organocobaloximes: Crystal structure and Co-C bond reactivity study
Chadha, Preeti,Gupta,Mahata, Kingsuk
, p. 92 - 98 (2008/10/09)
The insertion of sulfur dioxide into the Co-C bond in ArCH 2Co(dioxime)2Py forms a mixture of ArCH2SO 2Co(dioxime)2Py, ClCo(dioxime)2Py, and a neutral trinuclear complex, [(dpgH)2PyCoIII-μ-SO 3]2-CoII(MeOH)4. The inserted products 4-CN-C6H4CH2SO2Co(dpgH) 2Py and C6H5CH2SO 2Co(gH)2Py and the trinuclear complex have been structurally characterized by X-ray for the first time. The insertion of sulfur dioxide into the Co-C bond affects the orientation of the benzyl group.
